ORGNMonday, March 24, 2003

8:00 PM-10:00 PM Convention Center -- Hall G,Sci-Mix
Sci-Mix
Organizer:L. McElwee-White
 61Application of a flexible, asymmetric synthesis of (5R)-thiolactomycin to develop new inhibitors of type I fatty acid synthase
Jill M. McFadden, Susan M. Medghalchi, Jagan N. Thupari, Michael L. Pinn, Aravinda Vadlamudi, Katherine I. Miller, Francis P. Kuhajda, Craig A. Townsend
 72Synthesis of D-leucine derived PNA monomers: DiSC2(5) aggregate formation on modified PNA/DNA templates
Rojendra Singh, Isil Dilek, Bruce Armitage
 76A new electron acceptor for supramolecular chemistry
Kathryn A. McMenimen, Joseph B. Carroll, Vincent M. Rotello, Thibaut Jarrosson, Darren G. Hamilton
 78Water-soluble calix[4]arenes for molecular recognition and encapsulation
Suazette N. Reid, Suzanne B. Shuker
 83Porphyrin-appended anion receptors
Stephen D. Starnes, Sailaja Arungundram, Colene H. Saunders, Jeff C. Harper
 86Molecular assembly of 1,2- and 1,3-bis(cyanomethyl)benzene with silver salts
Gerardo Marquez, Douglas M. Ho, Kathleen V. Kilway
 89Origins of selectivity in noncovalent molecular imprinted polymers
Ryan L. Simon, Jason N. Campbell, David A. Spivak
 92Guest-induced chirality in a self-assembled capsule
Alessandro Scarso, Julius Rebek, Alexander Shivanyuk, Osamu Hayashida
 94Construction of a nanoscale molecular muscle based on molecular recognition
Ja-Young Han, J Fraser Stoddart
 99Magic ring rotaxanes via olefin metathesis
Robert H. Grubbs, Stuart J. Cantrill, Andreas F. M. Kilbinger, Andrew W. Waltman, Erin N. Guidry
 104Conjugation of poor inhibitors of carbonic anhydrase with surface binding groups: A strategy to improve inhibitor efficiency
Bidhan C. Roy, Ryan Hegge, Theresa A. Rosendahl, Xiao Jia, Sanku Mallik
 110A facile procedure for determining the pKa of weakly acidic pharmaceutical drugs and supramolecular ligands
Arno Kraft
 113Synthesis of carbohydrate derivatives using clean chemistry
Rachel N. MacCoss, Paul E. Brennan, Steven V. Ley
 114Total synthesis and antileukemic activity of the novel fatty acid 2-methoxy-14-methylpentadecanoic acid
Néstor M. Carballeira, Heidyleen Cruz, Elsie A. Orellano, Fernando A. González
 118Nonactin biosynthesis: Nonactin is cleaved by a serine esterase-like protein encoded by the nonactin resistance gene, nonR
James E. Cox, Nigel D. Priestley
 123Detection of dsDNA in homogeneous solution by hairpin polyamide-tetramethyl rhodamine conjugates
Victor C. Rucker, Alex R. Dunn, Shantanu Sharmu, H. B. Gray, Jay R. Winkler, Peter B. Dervan
 128Design of novel fluorescence energy transfer cassettes utilizing a nucleobase as part of the donor
Guan-Sheng Jiao, Lars H. Thoresen, Kevin Burgess
 135A geomorphic classification of antibody binding sites
K. N. Houk, Michelle Lee, Julie Schallhorn, Keiki Sugimoto, Andrew G. Leach
 136A new strategy to induce g-turn: Peptides composed of alternating a-aminoxy acids and a-amino acids
Wei Li, Dan Yang
 147Suzuki cross-coupling using glass beads technology
Kokovi M. Lawson Daku, Jonathan M.J. Williams, Roger F. Newton
 153A solid-phase synthesis of diacylglycerol-lactones in macrokans as a prelude to the synthesis of protein kinase C isozyme-specific ligands by a combinatorial approach
Dehui Duan, Victor E. Marquez
 159Polymer-bound oxoammonium salt of TEMPO: A novel reagent for selective oxidation of alcohols
Sukanta Bhattacharyya, Lanchi Vo, Tejal Parekh, Jeff Labadie
 334Mono-deprotection of di-tert-butyl silylene ethers: A new protocol for selective protection of secondary alcohols
Brian L. Pagenkopf, Ming Yu
 344Eliminating aqueous workup in multiple-step solution-phase synthesis by flash chromatography
Shahnaz Ghassemi, Jack Liu, Peter Rahn
 346Studies toward the synthesis of streptovaricin D
José A. Prieto, Wildeliz Torres
 351Synthesis of dibenzo-14-crown-4 ethers bearing fluorinated alcohol sidearms
Frederick V. Sloop Jr., Peter V. Bonnesen
 354The aqueous Prins reaction
Danielle L. Aubele, Paul E Floreancig
 361Investigation of 2-isoxazoline synthesis: A unique twist on the Mitsunobu reaction
Genessa M. Wood, Cindy C. Browder
 363Epoxidation of D5-steroids by dioxiranes generated in situ
Edward J. Parish, Zhihai Qiu
 372Copper(I)-catalyzed synthesis of unsymmetrical triphenylphosphines
Derek Van Allen, D. Venkataraman
 373CsOH-promoted P-alkylation: A convenient and highly efficient synthesis of tertiary phosphines and their metal complexes
Matthew T. Honaker, Benjamin J. Sandefur, Alicia L. McDaniel, Lester L. Pesterfield, Ralph Nicholas Salvatore
 376An unexpected hydroxylation observed in selenoxide elimination reactions producing 4-hydroxy-conjugated carbonyl compounds
JiYoung Mun, Michael B. Smith
 381"Nonet-bracketing" in the 1H NMR spectrum: Quantification of low levels of water and other solutes in organic solutions
Thomas R. Hoye, Hollie J. Lewis, Seif-Eldin N. Ayyad
 395Cascade radical cyclizations of benzannulated enyne-allenes: Unusual cleavage of a benzene ring leading to twisted 1,1'-dialkyl-9,9'-bifluorenylidenes and spiro[1H-cyclobut[a]indene-1,9'-[9H]fluorenes]
Yonghong Yang, Jeffrey L. Petersen, Kung K. Wang
 398Synthesis of 2-aryl-benzo[b]furans via copper(I)-catalyzed coupling reaction of o-iodophenols and aryl acetylenes
Craig G. Bates, Pranorm Saejueng, Jaclyn Murphy, D. Venkataraman
 399b-cyclodextrin-controlled Reimer-Tiemann reaction for N,N-dimethylaniline
Jigang Pan, Yuejun Huang
 400Fluorous approach to synthesis and separation: Fluorous, chromatography-free Mitsunobu reaction
Roman Dembinski, Marcin W. Markowicz
 401Practical ligands for copper-catalyzed ether-forming reactions
David Mitchell, Y. John Pu, Thomas M Koenig, Zhonghui Wan
 403Study of the Corey-Kim intermediate by FT-IR
Gilles Chambournier, Herman Surjono, Zhenglong Xiao, Marius Naris
 408Progress toward the total synthesis of peloruside A
Tiffany N. Heady, Michael T. Crimmins
 421Progress toward the total synthesis of salvinorin A: A potent, non-nitrogenous k-opioid receptor selective agonist
Suryanarayana Vangapandu, Ashok Phillip, Jeremy D. Stewart, Jordan Zjawiony, Mitchell A. Avery, Christopher R. McCurdy
 424Efficient assembly of the oxazole subunit of leucascandrolide A
Jelena Janjic, Sergey A. Kozmin
 439Mechanistic studies of enantioselective conjugate radical additions
Jake Zimmerman, Shankar Manyem, Mukund P. Sibi
 447Development of nucleophilic chiral pyridine catalysts: Applications in asymmetric quaternary carbon synthesis
Edwin Vedejs, Scott A. Shaw
 453A new strategy for the use of chiral auxiliaries in asymmetric synthesis
Frederic J. Feuillet, Steven D. Bull
 455Novel stereoselective route to benzindene prostacyclins: The large-scale synthesis of RemodulinTM (treprostinil, UT-15)
James P. Staszewski, Robert M. Moriarty, Liang Guo, Raju Penmasta, Neena Rani, Sudersan M. Tuladhar, David Crich, Livia A. Enache, Om Prakash
 485Spectroscopic identification of carbene and carbenoid intermediates
Eric M. Tippmann, Matthew S. Platz
 487Chiral chemistry through confinement: Photocyclization of tropolone naphthalenone and cyclohexadienone derivatives included in zeolites
Lakshmi S. Kaanumalle, Ramamurthy Vaidhyanathan
 498Synthesis of novel macrocyclic polyamine complexes for use as anticancer prodrugs
Laurie L. Parker, David J. Robins
 502The quest for hydrocarbon analogs of the porphyrins
Denise A. Colby, T. D. Lash
 510Metallation in hydrocarbon solvents: The effect of electron density localization of the directing group
R. W. Holman, Michael Timmons, Roslyn LeMastus, Phillip Shelton, Gina Jackson, B.D. Woosley, S. Brown, S. Dumbris, A. Spencer, D.W Slocum
 514Dicationic electrophiles: Superacid-catalyzed chemistry of alkynes
Rendy Rendy, Yun Zhang, Aaron McElrea, Alma Gomez, Han Dang, Douglas A. Klumpp
 515Direct palladium-catalyzed route for isoxazole synthesis
Matthew B. Kraft, Cindy C. Browder
 523A simple and efficient route to N-functionalized dithieno[3,2-b:2',3'-d]pyrroles: Fused-ring building blocks for new conjugated polymeric systems
Katsu Ogawa, Seth C. Rasmussen
 528Synthesis of fluorescent rhodamine conjugates by reaction of primary amines with rhodamine 2'-esters
Jonathan Grote, Maciej Adamczyk
 530Novel polyphenylene structures related to "cubic graphite"
Xianfeng Shen, Douglas M. Ho, Robert A. Pascal Jr.
 536Inhibitor-releasing quinones for reversal photography
Thomas R. Welter
 541Dynamic NMR study of organosulfur compounds: Redox-mediated molecular brake
Parag V. Jog, Richard E. Brown, Dallas K. Bates
 543AlQ3 derivatives with tunable optical properties
Radek Pohl, Pavel Anzenbacher Jr.
 545Design and synthesis of new organometallic complexes with potential biological activity
Valerian Dragutan, Taeboem Oh, Alex Schultz, Tania Tasu, Ileana Dragutan, Mariana Danila, Petru Filip, Bernd Wrackmeyer, Larry R. Sherman
 548Photophysical and photochemical properties of a new class of photosensitizers for photodynamic therapy
Kevin D. Belfield, Claudia C. Corredor
 558Synthesis of photocleavable protecting groups for primary alcohols with applications in the construction of DNA microarrays
Garrett M. Zopp, Mary K. Boyd
 562NMR studies of the cleavage of highly substituted epoxides with organoalane reagents
José A. Prieto, Gerardo Torres
 570Mechanistic investigations of the aqueous breakdown of substituted N-(hydroxymethyl)benzamide compounds as a function of pH
Richard W. Nagorski, William J. Tenn III
 572The location effect of substituents on the Bronsted apha for hydride transfer reactions
In-Sook Han Lee, Kyoung Hwha Suh
 581Palladium-catalyzed synthesis of isatins and 2-haloisatogens
Chet R. Howerton, Björn C. G. Söderberg, Shubhada W. Dantale
 584Synthesis, characterization, and elaboration of endo[n.n.n.n] (n = 3 or 4) metacyclophanes
Dennis H. Burns, Charles L. Jayne, Sumith A. Kularatne
 591Ligand-controlled asymmetric induction at a transition-metal-bonded stereogenic carbon: Diastereoselective synthesis of oxapalladacycles and development of their synthetic applications
Helena C. Malinakova, Janelle L. Portscheller, Sara E. Lilley
 593Indium-promoted couplings leading to enediyne formation and oxy-cope rearrangements
Thomas M. Mitzel, Annie Troutman
 595Synthesis of lactones and related bicyclic heterocycles by palladium(II)-catalyzed 1,4-oxidation of conjugated dienes
Renzo C. Verboom, Anders Persson, Jan-E. Bäckvall

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 225th ACS National Meeting, New Orleans, LA, March 23-27, 2003