ORGN 35 |
| Justin Du Bois, Department of Chemistry, Department of Chemistry, Stanford University, Stanford, CA 94305-5080 |
| A central objective of our research program is aimed at the invention of highly selective oxidation reactions having general utility for the synthesis of amines and amine derivatives. These efforts have manifest in the development of a unique, catalytic C-H amination process that makes possible the facile and efficient oxidative cyclization of carbamate and sulfamate esters. The heterocyclic products obtained are themselves precursors to 1,2- and 1,3-amino alcohols as well as other functionalized amine structures. A general discussion of this C-H amination methodology and highlights of its application for the assembly of nitrogen-rich marine natural products will be presented. |
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Herbert C. Brown Award for Creative Research in Synthetic Methods
2:00 PM-4:40 PM, Sunday, March 23, 2003 Convention Center -- La Nouvelle Ballroom A/B, Oral
Division of Organic Chemistry |